PHOTOCHEMICAL CONTROL OF IONIC-CONDUCTION BY CROWNED SPIROBENZOPYRAN

被引:36
|
作者
KIMURA, K
YAMASHITA, T
YOKOYAMA, M
机构
关键词
D O I
10.1246/cl.1991.965
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ionic conduction in composite films incorporating a crowned spirobenzopyran and LiClO4 was controlled photochemically. UV light irradiation, which promotes the isomerization of spirobenzopyran to its corresponding merocyanine form, depressed Li+ conduction due to its enhanced Li+ complexation, while visible light irradiation restored the initial ionic conduction.
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页码:965 / 968
页数:4
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