N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline

被引：1
|
作者：
Ajibade, Peter A. [1 ]
Onwudiwe, Damian C. [1 ]
Omondi, Bernard [2 ]
机构：
[1] Univ Ft Hare, Dept Chem, ZA-5700 Alice, South Africa
[2] Univ KwaZulu Natal, Sch Chem & Phys, Westville Campus,Private Bag X54001, ZA-4000 Durban, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812048416
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C32H29NP2S2, has two molecules in the asymmetric unit, with an r.m.s. difference of 0.218 angstrom in their best-fit overlay. Bothlecules have a slightly distorted trigonal- planar N atom, bonded to two P-V atoms and a C atom of the 4-ethylphenyl unit. The P-N-P angles of 126.34 (11) and 125.98 (11)degrees are larger than the four C-N-P bond angles. The two S atoms are trans to one another with respect to the P-N-P angle. The crystal structure features C-H center dot center dot center dot pi interactions. The methyl group in one of the molecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).
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页码：O3491 / +
页数：16
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