THERMAL-DECOMPOSITION OF ALLYLIC SULFINIC ACIDS - A STUDY OF A RETRO-ENE TRANSITION-STATE

被引：6
|
作者：
HISCOCK, SD
ISAACS, NS
KING, MD
YOUNG, DJ
机构：
[1] UNIV READING, DEPT CHEM, READING RG6 2AD, BERKS, ENGLAND
[2] GRIFFITH UNIV, FAC SCI & TECHNOL, BRISBANE, QLD 4111, AUSTRALIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期
关键词：
D O I：
10.1039/c39940001381
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
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页码：1381 / 1382
页数：2
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