RHENIUM COMPLEXES FROM ALKYNES - X-RAY CRYSTAL-STRUCTURES OF RE-2(MU-2-ETA(1),ETA(4)-C(4)PH(4))(CO)(7) AND RE(C,O-CH=C[RE(CO)(4)(NME(3))]C(OME)O)(CO)(4)

被引：6

作者：

BRUCE, MI ^{[1
]}

LOW, PJ ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 02期

关键词：

RHENIUM; ALKYNE; CRYSTAL STRUCTURE; AMINE; CARBONYL; VINYL;

D O I：

10.1016/0022-328X(94)87273-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of Re-2(mu-2 eta(1),eta(4)-C(4)Ph(4))(CO)(7) obtained from Re-2(CO)(8)(NCMe), and C(2)Ph(2), consists of an Re-2(CO)(7) unit [Re-Re 2.874(1) Angstrom] bridged by a 2 eta(1),eta(4)-C(4)Ph(4) ligand, as proposed by earlier workers. Methyl propiolate is inserted into the Re-Re bond of Re-2(CO)(9)(NCMe), as shown by the molecular structure of the NMe(3) derivative of the product; the NMe(3) Ligand is attached to the non-chelated Re atom [Re-N 2.31(1) Angstrom].

引用

页码：191 / 195

页数：5

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