(2,2'-BIPYRIDINE)BIS(THIOCYANATO-N)-COPPER(II), [CU(BIPY)(NCS)(2)]

被引：6
|
作者：
PARKER, OJ
WILSON, BL
BRENEMAN, GL
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S0108270194006980
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure,of green [Cu(bipy)(NCS)(2)] (bipy = 2,2'-bipyridine, C10H8N2) containing six-coordinate copper(II) with a tetragonal [(CuN4S2)-N-II] core is reported. The Cu to N(NCS) distance is 1.946 (3) Angstrom with Cu bonded to the N-atom end of two thiocyanate ligands occupying two of the four equatorial positions. The two remaining short bonds in the tetragonal core are Cu-N(bipy) bonds to the 2,2'-bipyridine ligand [1.998 (2) Angstrom]. The long axial bonds to the Cu center involve S atoms from neighboring [Cu(bipy)(NCS)(2)] units with a Cu-S(SCN) distance of 3.220 (1) Angstrom.
引用
收藏
页码：1681 / 1683
页数：3
相关论文
共 50 条
  • [21] Crystal structure and magnetic properties of the single-μ-chloro copper(II) chain [Cu(bipy)Cl2] (bipy = 2,2′-bipyridine)
    Hernández-Molina, M
    González-Platas, J
    Ruiz-Pérez, C
    Lloret, F
    Julve, M
    INORGANICA CHIMICA ACTA, 1999, 284 (02) : 258 - 265
  • [22] [μ-N,N′-bis(3-aminopropyl)oxamidato(2-)]-bis[(2,2′-bipyridine)copper(II)] dinitrate
    Boyd, Peter D. W.
    Rickard, C. E. F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M3200 - M3202
  • [23] CRYSTAL STRUCTURE OF PERCHLORATO-BIS(2,2'-BIPYRIDINE)-COPPER(II) PERCHLORATE, [CU(CLO4)(BIPY)2]CLO4
    NAKAI, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1971, 44 (09) : 2412 - +
  • [24] REACTIONS OF PENTAFLUOROPHENYLTRIMETHYLSILANE WITH BIS(2,2'-BIPYRIDINE)COPPER(II) FLUORIDE
    SONODA, H
    SONODA, T
    KOBAYASHI, H
    NIPPON KAGAKU KAISHI, 1985, (10) : 2051 - 2053
  • [25] Bis(2,2′-bipyridine N,N′-dioxide)bis(tricyanomethanido)manganese(II)
    Luo, Jun
    Yang, Feng
    Qiu, Li-Juan
    Wang, Xin-Xia
    Liu, Bao-Shu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M547 - U761
  • [26] Thermal and photo control of the linkage isomerism of bis(thiocyanato)(2,2′-bipyridine)platinum(II)
    Kishi, S
    Kato, M
    INORGANIC CHEMISTRY, 2003, 42 (26) : 8728 - 8734
  • [27] Bis(3,5-dimethylpyrazole-N2)bis(thiocyanato-N)cobalt(II) monohydrate
    Chen, XF
    Liu, SH
    You, XZ
    Fun, HK
    Chinnakali, K
    Razak, IA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 22 - 24
  • [28] Bis(2,2′-bipyridine-κ2N,N′)dibromidocadmium(II)
    Zhang, Bi-Song
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1413 - U1559
  • [29] Bis(2,2′-bipyridine-κ2N,N′)dibromidocadmium(II)
    Zhu, Jian-Wei
    Yang, E.
    Song, Xu-Chun
    Lin, You-Dan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1044 - M1045
  • [30] CRYSTAL STRUCTURE OF NITRATO-BIS(2,2'-BIPYRIDINE)COPPER(II) NITRATE MONOHYDRATE CU(NO3)(BIPY)2!NO3.H2O
    NAKAI, H
    OOI, S
    KUROYA, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (02) : 577 - &
12345