THE REACTIVITY OF PD(PTBU3)2 TOWARDS THE OXONIUM ION - CRYSTAL-STRUCTURE OF TRANS-[(TBU3P)2PD(H)(CH3CN)]BPH4

被引：18

作者：

SOMMOVIGO, M

PASQUALI, M

LEONI, P

SABATINO, P

BRAGA, D

机构：

[1] DIPARTIMENTO CHIM G CIAMICIAN,VIA SELMI 2,I-40126 BOLOGNA,ITALY

[2] DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[3] SCUOLA NORMALE SUPER PISA,I-56100 PISA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 418卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)86352-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Pd(PtBu3)2 with the strong acids H3O+ X-, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-[(tBu3P)2Pd(H)(H2O)]X. The thermally stable hydrides trans-[(tBu3P)2Pd(H) (CH3CN)]X were obtained by substitution of the water molecule by CH3CN. The reaction of the aquo-hydrides with CO, yielding [Pd(CO)(PtBu3)]2 and the crystal structure of trans[[(tBu3P)2Pd(H) (CH3CN)]BPh4 are also reported.

引用

页码：119 / 126

页数：8

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