SYNTHESES AND STRUCTURES OF FUNCTIONAL SUBSTITUTED FERROCENES

被引：10
|
作者：
GRUNHAGEN, A [1 ]
PIEPER, U [1 ]
KOTTKE, T [1 ]
ROESKY, HW [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 04期
关键词：
N; O-BIS(TRIMETHYLSILYL)FERROCENYLIMIDATE; E; Z-(FERROCENYL-TRIMETHYLSILOXYMETHYLIDEN)TRIMETHYLSILYLPHOSPHANE;
D O I：
10.1002/zaac.19946200422
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Substituted ferrocenes have been prepared using carbonic acid chloride of ferrocene. New pathways have been found reacting the acid chloride with sodium hexamethyldisilazane and tris(trimethylsilyl)phosphane, respectively. The compounds FecC(OSiMe3)N(SiMe3) (Fec = C5H5FeC5H4) 1 and FecC(OSiMe3)P(SiMe3) 2 have been obtained and characterized by X-ray single crystal structure analysis. Experiments for the preparation of FecCP 3 are reported.
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页码：716 / 722
页数：7
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