POLYMERIZATION OF METHYL-METHACRYLATE USING ISATIN AND BENZOYL PEROXIDE COMBINATION AS PHOTOINITIATOR

被引：7
|
作者：
SOM, PK [1 ]
BANERJEE, AN [1 ]
机构：
[1] UNIV CALCUTTA,DEPT PLAST & RUBBER TECHNOL,92 APC RD,CALCUTTA 700009,W BENGAL,INDIA
来源：
EUROPEAN POLYMER JOURNAL | 1993年 / 29卷 / 06期
关键词：
D O I：
10.1016/0014-3057(93)90344-F
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photopolymerization of methyl methacrylate in visible light was studied at 40-degrees under N2 using isatin-(benzoyl peroxide) combination as the initiator The photopolymerization by a free radical mechanism and radicals are generated by an initial complexation between the initiator components and the monomer. Kinetic data indicate a low order dependence of R(p) on initiator concentration (initiator exponent <0.5) Initiator-dependent chain termination was significant, with bimolecular termination.
引用
收藏
页码：889 / 892
页数：4
相关论文
共 50 条
12345