ARE THE TEXTBOOK ANIONS O2-, [CO3]2-, AND [SO4]2- FICTITIOUS

被引：53
|
作者：
JANOSCHEK, R
机构：
[1] Institut für Theoretische Chemie Universität, Graz, A-8010
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 616卷 / 10期
关键词：
EXISTENCE OF DIANIONS (O2-; CO3]2-; SO4]2-); ABINITIO CALCULATIONS;
D O I：
10.1002/zaac.19926161016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Experimental second electron affinities are still unknown for the title anions. It will be shown by means of quantum chemical ab initio calculations that these dianions are unstable with respect to spontaneous ionization. They all must be designated as non-existent.
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页码：101 / 104
页数：4
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