SYNTHESIS OF OXAZEPINONES FROM VINYLOXIRANES AND CHLOROSULFONYL ISOCYANATE

被引：3
|
作者：
DANIEL, J [1 ]
SHUKLA, D [1 ]
DHAR, DN [1 ]
机构：
[1] INDIAN INST TECHNOL, DEPT CHEM, KANPUR 208016, UTTAR PRADESH, INDIA
来源：
CHEMISTRY LETTERS | 1992年 / 08期
关键词：
D O I：
10.1246/cl.1992.1575
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile synthesis of oxazepinone derivatives is reported by the interaction of vinyloxiranes and chlorosulfonyl isocyanate. A 1,5 to 1,7 - dipolar rearrangement of the initially formed adduct, followed by ring closure is proposed.
引用
收藏
页码：1575 / 1578
页数：4
相关论文
共 50 条
  • [21] REACTION OF CHLOROSULFONYL ISOCYANATE WITH UNSATURATED SUGARS
    HALL, RH
    JORDAAN, A
    LOURENS, GJ
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (01): : 38 - 44
  • [22] CHLOROSULFONYL ISOCYANATE - AN UNUSUAL CHLORINATING AGENT
    SRINIVASAN, TN
    RAO, KR
    SATTUR, PB
    SYNTHETIC COMMUNICATIONS, 1986, 16 (05) : 543 - 546
  • [23] RECENT ADVANCES IN THE CHEMISTRY OF CHLOROSULFONYL ISOCYANATE
    DHAR, DN
    MURTHY, KSK
    SYNTHESIS-STUTTGART, 1986, (06): : 437 - 449
  • [24] Direct carboxamidation of sydnones with chlorosulfonyl isocyanate
    Turnbull, K
    Gross, KC
    Hall, TA
    SYNTHETIC COMMUNICATIONS, 1998, 28 (05) : 931 - 937
  • [25] HETEROCYCLES FROM CHLOROSULFONYL ISOCYANATE .2. REACTION WITH ISOTHIOUREAS
    KARADY, S
    AMATO, JS
    DORTMUND, D
    PATCHETT, AA
    REAMER, RA
    TULL, RJ
    WEINSTOCK, LM
    HETEROCYCLES, 1979, 12 (09) : 1199 - 1202
  • [26] REACTION OF CHLOROSULFONYL ISOCYANATE WITH ALLENES AND OLEFINS
    MORICONI, EJ
    KELLY, JF
    JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (08): : 3036 - &
  • [27] INFRARED AND RAMAN SPECTRA OF CHLOROSULFONYL ISOCYANATE
    KANESAKA, I
    KAWAI, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (10) : 3298 - +
  • [28] Application of Chlorosulfonyl Isocyanate (CSI) in the Synthesis of Fused Tetracyclic Ketone Ring Systems
    VanNatta, Jennifer M.
    Niu, Haichan
    Carlson, Graham J.
    Pinney, Kevin G.
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (21): : 15636 - 15651
  • [29] A concise synthesis of (-)-cytoxazone and (-)-4-epi-cytoxazone using chlorosulfonyl isocyanate
    Kim, In Su
    Kim, Ji Duck
    Ryu, Chae Baek
    Zee, Ok Pyo
    Jung, Young Hoon
    TETRAHEDRON, 2006, 62 (40) : 9349 - 9358
  • [30] ADDITION OF CHLOROSULFONYL ISOCYANATE TO ALPHA AND BETA PINENE
    MALPASS, JR
    TETRAHEDRON LETTERS, 1972, (49) : 4951 - &
12345