HYDROGEN-BONDS AS A CRYSTAL DESIGN ELEMENT FOR ORGANIC MOLECULAR-SOLIDS WITH INTERMOLECULAR FERROMAGNETIC INTERACTIONS

被引：0
|
作者：
HERNANDEZ, E [1 ]
MAS, M [1 ]
MOLINS, E [1 ]
ROVIRA, C [1 ]
VECIANA, J [1 ]
机构：
[1] INST CIENCIA MAT BARCELONA,CAMPUS UAB,E-08193 BARCELONA,SPAIN
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 06期
关键词：
D O I：
10.1002/anie.199308821
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
O-H ... O-N and H2C-H ... O-N hydrogen bonds determine the arrangement of the stable radical 1 in the solid state. This leads to a system with intermolecular ferromagnetic interactions still rare in solids composed of exclusively organic compounds. The experimental findings are consistent with properties for solid 1 predicted by MO calculations and geometric considerations.
引用
收藏
页码：882 / 884
页数：3
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