PREFERRED CONFORMATION OF C-GLYCOSIDES .8. SYNTHESIS OF 1,4-LINKED CARBON DISACCHARIDES

被引:0
|
作者
YUAN, W [1 ]
BABIRAD, SA [1 ]
KISHI, Y [1 ]
机构
[1] HARVARD UNIV,DEPT CHEM,12 OXFORD ST,CAMBRIDGE,MA 02138
来源
JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 02期
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three general synthetic routes to 1,4-linked carbon disaccharides (e.g., 3, 4, 15-17, 21-23, 44, and 45) are presented. Control of the stereochemistry at C.1', C.2', C.5', and C.4, the incorporation of deuterium labels at the C.alpha position, and structural modifications of the right-hand ring are addressed.
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页码:468 / 481
页数:14
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