Palladium-Catalysed Coupling and Acid-Mediated Cyclisation: Synthesis of Fluorenones and Fluorenes

被引：4
|
作者：
Kumar, Devarapalli Ravi [1 ]
Kishore, Dakoju Ravi [1 ]
Satyanarayana, Gedu [1 ]
机构：
[1] Indian Inst Technol Hyderabad, Dept Chem, Sangareddy 502285, Telangana, India
来源：
SYNOPEN | 2018年 / 2卷 / 04期
关键词：
Friedel-Crafts; cyclocarbonylation; fluorenone; fluorine;
D O I：
10.1055/s-0037-1610663
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalysed sequential one-pot synthesis of fluorenones is described. The reaction comprises intermolecular Suzuki coupling and intramolecular acid-mediated cyclisation in a one-pot procedure. The protocol is also applied to the synthesis of fluorenes using a single column purification.
引用
收藏
页码：268 / 275
页数：8
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