THE FELKIN-ANH RULE IN RADICAL CHEMISTRY - 1,2-STEREOINDUCTION IN RADICAL-ADDITION TO ALKENES

被引:1
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作者
GIESE, B
DAMM, W
ROTH, M
ZEHNDER, M
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Alkyl radicals add to chiral alkene 4 [(S)-3-phenyl-1-butene-1,1-dicarbonitrile] stereoselectively. anti-Isomers 5a-c are formed as the major products. This stereoinduction cannot be interpreted by the stability of the different conformers of alkene 4, but is rationalized by the Felkin-Anh model.
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页码:441 / 443
页数:3
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