HYPERFINE FIELDS IN IRON DILUTE ALLOYS AND INTERNAL OXIDATION

被引:0
|
作者
SILVA, MTX
VASQUEZ, A
机构
[1] Instituto de Física-UFRGS, Porto Alegre
来源
HYPERFINE INTERACTIONS | 1991年 / 66卷 / 1-4期
关键词
D O I
10.1007/BF02395881
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
An Fe-V 2.5 at% foil was annealed at various temperatures in the range from 120-degrees-C to 1000-degrees-C for 10 min and analysed by Transmission Mossbauer Spectroscopy (TMS) and Conversion Electron Mossbauer Spectroscopy (CEMS) after each thermal process. A computational method to fit the spectra to obtain a parameter related to the concentration of the alloy was studied and applied to the data. No surprising effects were found on the bulk measurements (TMS), but there is a clear decrease of the alloy concentration in the 550-degrees-C to 700-degrees-C annealing temperature range, observed for the surface analysis (CEMS measurements). The phenomenon was attributed to the preferential internal oxidation of vanadium atoms in this range of temperature. Probably some vanadium oxide decomposition occurs at higher temperatures, recovering the original state of the sample.
引用
收藏
页码:325 / 329
页数:5
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