PHOTOCHEMISTRY OF POLYHALOARENES .11. THE PHOTOCHEMISTRY OF 3 TETRACHLORONAPHTHALENES

被引:2
|
作者
FREEMAN, PK
CLAPP, GE
STEVENSON, BK
机构
[1] Department of Chemistry, Oregon State University Corvallis
关键词
D O I
10.1016/S0040-4039(00)93535-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The regiochemistry of the photolysis of three tetrachloronaphthalenes is sharply dependent upon the presence of triethylamine. Analysis of the steady state kinetics in the presence and absence of quenchers and of triethylamine provides a mechanistic rationale in terms of triplet, triplet excimer, and singlet exciplex.
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页码:5705 / 5708
页数:4
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