FACILE ENANTIOSELECTIVE SYNTHESIS OF 2 NEW BICYCLIC CHIRAL TEMPLATES

被引：7
|
作者：
BELFIELD, KD
SEO, J
机构：
[1] Department of Chemistry, University of Detroit Mercy, Detroit, MI 48219
来源：
SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 04期
关键词：
D O I：
10.1080/00397919508011379
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active bicyclic dienes, 4 and 5 have been enantioselectively prepared in three and four steps, respectively. Mixtures of predominantly either the R or S enantiomer were obtained via an asymmetric alkylation of a chiral enamine.
引用
收藏
页码：461 / 466
页数：6
相关论文
共 50 条
  • [41] Bicyclic guanidine-catalyzed enantioselective phospha-Michael reaction:: synthesis of chiral β-aminophosphine oxides and β-aminophosphines
    Fu, Xiao
    Jiang, Zhiyong
    Tan, Choon-Hong
    CHEMICAL COMMUNICATIONS, 2007, (47) : 5058 - 5060
  • [42] ENANTIOSELECTIVE CATALYTIC REDUCTIONS OF KETONES - SYNTHESIS AND APPLICATION OF A NEW STRUCTURALLY RIGID BICYCLIC CATALYST
    WALLBAUM, S
    MARTENS, J
    TETRAHEDRON-ASYMMETRY, 1991, 2 (11) : 1093 - 1096
  • [43] Synthesis and reactivity of new chiral bicyclic phospholanes as acyl-transfer catalysts
    MacKay, JA
    Vedejs, E
    JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (02): : 498 - 503
  • [44] Chiral non-racemic bicyclic lactams: Templates for the asymmetric synthesis of chiral quaternary stereocenters - An application toward the total synthesis of (-)-trisporol B, trisporic acids and their derivatives
    Reader, MR
    Meyers, AI
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U514 - U514
  • [45] STEREOCONTROLLED SYNTHESIS OF SUBSTITUTED PYRROLIDINES AND PYRROLIDINONES - A NEW APPLICATION OF CHIRAL BICYCLIC LACTAMS
    ENNIS, MD
    HOFFMAN, RL
    GHAZAL, NB
    MOONEY, PA
    JANSEN, PI
    CHIDESTER, CG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 33 - ORGN
  • [46] Enantioselective Synthesis of the ent-Lomaiviticin A Bicyclic Core
    Feldman, Ken S.
    Selfridge, Brandon R.
    ORGANIC LETTERS, 2012, 14 (21) : 5484 - 5487
  • [47] A Bioinspired Strategy for the Enantioselective Synthesis of Bicyclic Oxygen Heterocycles
    Venegas, Edith Rodriguez
    Willis, Christine L.
    ORGANIC LETTERS, 2020, 22 (07) : 2548 - 2552
  • [48] Synthesis and Applications of Chiral Bicyclic Bisborane Catalysts
    Yang, Zhao-Ying
    Zhang, Ming
    Wang, Xiao-Chen
    SYNTHESIS-STUTTGART, 2022, 54 (06): : 1527 - 1536
  • [49] Synthesis of chiral polyhydroxylated bicyclic traizolines.
    Norris, P
    Horton, D
    Giridhar, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 537 - CHED
  • [50] SYNTHESIS OF CHIRAL INDOLIZINES AS BICYCLIC ERGOLINE ANALOGS
    GMEINER, P
    HETEROCYCLES, 1991, 32 (08) : 1499 - 1504
12345