Tetraaquabis[2-(2-nitrophenyl)acetato-kappa O]cobalt(II)

被引:5
|
作者
Danish, Muhammad [1 ]
Tahir, Muhammad Nawaz [2 ]
Iftikhar, Sana [1 ]
Raza, Muhammad Asam [1 ]
Ashfaq, Muhammad [1 ]
机构
[1] Univ Gujrat, Inst Chem & Biol Sci, Dept Chem, Gujrat 50700, Pakistan
[2] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan
关键词
crystal structure; cobalt(II) complex; hydrogen bonding;
D O I
10.1107/S2056989015002467
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecule of the title compound, [Co(C8H6NO4)(2)(H2O)(4)], is centrosymmetric. It is a cobalt(II)complex, bearing two (2-nitrophenyl) acetate and four aqua ligands. The coordination around the Co-II atom is distorted octahedral, defined by four O atoms of water molecules in the equatorial plane and by two carboxylate O atoms at axial positions. The dihedral angles between the benzene ring and the acetate and nitro groups are 61.90 (10)and 19.21 (11)degrees, respectively. The water molecules form O-H center dot center dot center dot O hydrogen bonds with the nitro and carboxylate groups, leading to a layered structural arrangement parallel to (001).
引用
收藏
页码:M59 / +
页数:8
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