Tetraaquabis[2-(2-nitrophenyl)acetato-kappa O]cobalt(II)

被引：5

作者：

Danish, Muhammad ^{[1
]}

Tahir, Muhammad Nawaz ^{[2
]}

Iftikhar, Sana ^{[1
]}

Raza, Muhammad Asam ^{[1
]}

Ashfaq, Muhammad ^{[1
]}

机构：

[1] Univ Gujrat, Inst Chem & Biol Sci, Dept Chem, Gujrat 50700, Pakistan

[2] Univ Sargodha, Dept Phys, Sargodha, Punjab, Pakistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; cobalt(II) complex; hydrogen bonding;

D O I：

10.1107/S2056989015002467

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title compound, [Co(C8H6NO4)(2)(H2O)(4)], is centrosymmetric. It is a cobalt(II)complex, bearing two (2-nitrophenyl) acetate and four aqua ligands. The coordination around the Co-II atom is distorted octahedral, defined by four O atoms of water molecules in the equatorial plane and by two carboxylate O atoms at axial positions. The dihedral angles between the benzene ring and the acetate and nitro groups are 61.90 (10)and 19.21 (11)degrees, respectively. The water molecules form O-H center dot center dot center dot O hydrogen bonds with the nitro and carboxylate groups, leading to a layered structural arrangement parallel to (001).

引用

页码：M59 / +

页数：8

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