Studies of some uni-bivalent ion exchange reaction systems using strongly basic anion exchange resin, Indion-102

被引:0
|
作者
Singare, P. U. [1 ]
Lokhande, R. S. [2 ]
Nadar, M. B. [3 ]
机构
[1] Bhavans Coll, Dept Chem, Mumbai 58, Maharashtra, India
[2] Univ Mumbai, Dept Chem, Mumbai 98, Maharashtra, India
[3] SIES Coll Arts Sci & Commerce, Dept Chem, Mumbai 22, Maharashtra, India
关键词
Ion exchange equilibrium; Equilibrium constant; Enthalpy; Endothermic reactions; Anion exchange; Indion-102;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The study on thermodynamics of ion exchange equilibrium for uni-bivalent Cl-/SO42- and Cl-/C2O42- reaction systems was carried out using ion exchange resin Indion-102. The equilibrium constant K was calculated by taking into account the activity coefficient of ions both in solution as well as in the resin phase. The K values calculated for Cl-/SO42- and Cl-/C2O42- reaction systems were observed to decrease with rise in temperature having enthalpy values of 16.28 and 16.14 kJ/mol respectively, indicating endothermic ion exchange reactions.
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页码:879 / 883
页数:5
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