SYNTHESIS AND CRYSTAL-STRUCTURE OF NA10[P4(NH)6N4](NH2)6(NH3)0.5 WITH AN ADAMANTANE-LIKE ANION [P4(NH)6N4]4-

被引：26

作者：

JACOBS, H

POLLOK, S

GOLINSKI, F

机构：

[1] Fachbereich Chemie der, Universität Dortmund, Dortmund

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 07期

关键词：

SODIUM IMIDO NITRIDO PHOSPHATE(V); PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19946200714

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of Na10[P4(NH)6N4](NH2)6(NH3)0.5 were obtained by the reaction Of P3N5 with NaNH2 (molar ratio 1: 20) within 5 d at 600-degrees-C in autoclaves. The following data characterize X-ray investigations: Fm3mBAR, Z = 8, a = 15.423(2) angstrom, Z(F-0(2)) = 261 with F-0(2) greater-than-or-equal-to 3 sigma(F-0(2)) Z(Variables) = 27, R/R(w) = 0.086/0.089 The compound contains the hitherto unknown anion [P4(NH)6N4]4-, which resembles adamantane. The total structure can be described as follows: The centers of gravity of units of [Na8(NH2)6(NH3)]2+ - 8Na+ on the corners of a cube, 6NH2- on the ones of an inscribed octahedron with NH3 in the center - follow the motif of a cubic-closest packed arrangement. Units of [Na12(NH2)6]6+ - 12Na+ on the corners of a cuboctahedron and 6NH2- on the ones of an inscribed octahedron - occupy all octahedral and those of [P4(NH)6N4]4- all tetrahedral sites.

引用

页码：1213 / 1218

页数：6

共 50 条

[21] Synthesis, structure and spectroscopic investigations of two new organic-inorganic hybrids NH3(C6H4)2NH3CuCl4 and NH3(C6H4)2NH3HgCl4
Belhouchet, M.
Wamani, W.
Mhiri, T.
2ND INTERNATIONAL CONFERENCE ON MATERIALS PHYSICS AND APPLICATIONS (JIPMA 2009/MATERIAUX 2009), 2010, 13
[22] Ammonolysis reaction of (NH4)(2)GeF6 - Synthesis and structure of NH4[Ge(NH3)F-5]
Weber, W
Schweda, E
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (10): : 1529 - 1534
[23] LATTICE-DYNAMICS OF [NI(NH3)6](CLO4)2[NI(NH3)6](BF4)2, AND [NI(NH3)6](PF6)2
KULCZYCKI, A
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1981, 103 (02): : 753 - 756
[24] CRYSTAL-STRUCTURE OF HEXAMINE CYCLOTRIPHOSPHAZENE, P3N3(NH2)6
GOLINSKI, F
JACOBS, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (06): : 965 - 968
[25] CRYSTAL STRUCTURE OF (ZN(NH3)4)(OSO3N)2 AND (CD(NH3)4)(OSO3N)2
MULLER, A
BOSCHEN, I
SIEVERT, W
ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1970, B 25 (03): : 311 - &
[26] SYNTHESIS, CRYSTAL-STRUCTURE, AND PROPERTIES OF TETRAAMINOPHOSPHONIUM IODIDE[P(NH2)(4)]I
HORSTMANN, S
SCHNICK, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (10): : 1381 - 1386
[27] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE FIRST TETRAAMINOPHOSPHONIUM SALT P(NH2)(4)I
SCHNICK, W
HORSTMANN, S
SCHMIDPETER, A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07): : 785 - 786
[28] Synthesis, crystal structure and spectroscopic investigations of a new tetrachloridozincate NH3(C6H4)2NH3ZnCl4
Wamani, W.
Belhouchet, M.
Mhiri, T.
MATERIAUX 2010, 2012, 28
[29] THE CONDENSATION OF TETRAAMIDOPHOSPHONIUM CHLORIDE, [P(NH2)4]CL, IN THE DIVERS SYSTEM NH3/NH4CL UNDER PRESSURE
SCHADOW, H
THOMAS, B
LEHMANN, HA
MEZNIK, L
ZEITSCHRIFT FUR CHEMIE, 1984, 24 (12): : 445 - 446
[30] PHOSPHORUS NITROGEN-COMPOUNDS .54. THE REACTIONS OF GEMINAL N3P3(NH2)2CL4 AND OF N3P3(NH2)CL5 WITH ALKOXIDE IONS IN ALCOHOLS - THE GEMINAL =P(NH2)2 TO NON-GEMINAL=P(NH2)(OR) REARRANGEMENT - THE CRYSTAL-STRUCTURES OF TRANS-N3P3(NH2)2(OPRN)4, CIS-N3P3(NH2)2(OME)4, AND GEMINAL N3P3(NH2)2(OME)4
FINCHAM, JK
PARKES, HG
SHAW, LS
SHAW, RA
HURSTHOUSE, MB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (05): : 1169 - 1178

← 1 2 3 4 5 →