Bis(3-chlorobenzoato-kappa O-2,O ')bis-(nicotinamide-kappa N)copper(II)

被引：3

作者：

Bozkurt, Nihat ^{[1
]}

Dilek, Nefise ^{[2
]}

Delibas, Nagihan Caylak ^{[3
]}

Necefoglu, Hacali ^{[1
]}

Hokelek, Tuncer ^{[4
]}

机构：

[1] Kafkas Univ, Dept Chem, TR-63100 Kars, Turkey

[2] Aksaray Univ, Dept Phys, TR-68100 Aksaray, Turkey

[3] Sakarya Univ, Dept Phys, TR-54187 Sakarya, Turkey

[4] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813014694

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title Cu-II complex, [Cu(C7H4ClO2)(2)(C6H6N2O)(2)], contains two 3-chlorobenzoate (CB) and two nicotinamide (NA) ligands; the CB act as bidentate ligands, while the NA are monodentate ligands. The resulting CuN2O4 coordination polyhedron is a considerably distorted octahedron. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 17.92 (12) and 24.69 (16)degrees, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 52.20 (8) and 1.56 (6)degrees. In the crystal, N-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. The pi-pi contact between the benzene rings [centroid-centroid distance = 3.982 (2) angstrom] may further stabilize the crystal structure.

引用

页码：M356 / +

页数：10

共 50 条

[31] Bis(methacrylato-kappa O)bis(2,4,6-trimethylpyridine-kappa N)copper(II)
Ejaz
Khan, Islam Ullah
Murtaza, Alina
Harrison, William T. A.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M469 - +
[32] Crystal structure of trans-diaquabis(nicotinamide-kappa N-1)bis(4-nitrobenzoato-kappa O)manganese(II)
Askin, Gulcin Sefiye
Necefoglu, Hacali
Tonbul, Ali Murat
Dilek, Nefise
Hokelek, Tuncer
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 656 - +
[33] (Acetato-kappa O-2,O ')(acetato-kappa O)bis(2-amino-3-methylpyridine-kappa N-1)cobalt(II)
Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1260 - +
[34] Bis(mu-4-formylbenzoato-kappa(2) O:O ') bis[(4-formylbenzoato-kappa(2) O, O ') bis(isonicotin-amide-kappa N-1) copper(II)]
Sertcelik, Mustafa
Delibas, Nagihan Caylak
Necefoglu, Hacali
Hokelek, Tuncer
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M290 - +
[35] Tetrakis(mu-2-phenylquinoline-4-carboxylato-kappa O-2: O ')bis[(methanol-kappa O)copper(II)]
Guo, Junfang
Yan, Guoping
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1296 - +
[36] Crystal structure of bis(mu-4-nitrobenzoato-(KO)-O-2:O ')-bis[bis(4-methylpyridine-kappa N)(4-nitrobenzoato-kappa O-2,O ')manganese(II)]
Bharali, Sourav J.
Bora, Sanchay J.
Das, Birinchi K.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1549 - +
[37] (mu-Acetato-kappa O-2:O')[mu-2,6-bis({bis[(pyridin-2-yl-kappa N)methyl]amino-kappa N}methyl)-4-methylphenolato-kappa O-2:O](methanol-kappa O)dizinc bis(perchlorate)
Das, Biswanath
Haukka, Matti
Nordlander, Ebbe
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M120 - +
[38] Bis(3-acetylpyridine-kappa N)bis(methanol-kappa O)bis(thiocyanato-kappa N)nickel(II)
Werner, Julia
Boeckmann, Jan
Jess, Inke
Naether, Christian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M441 - +
[39] Bis(mu-hydroxido-kappa O-2:O)bis[bis(5-carboxypyridine-2-carboxylato-kappa N-2,O-2)iron(III)] dihydrate
Cao, Wenhai
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M625 - +
[40] Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)
Kani, Ibrahim
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M265 - U414

← 1 2 3 4 5 →