THE SYNTHESIS OF CHIRAL-ALPHA,BETA-UNSATURATED AND ARYL OXAZOLINES FROM KETONES AND AROLS VIA THEIR TRIFLATES AND PD-CATALYZED CO AND AMINO ALCOHOL COUPLING

被引：21

作者：

MEYERS, AI

ROBICHAUD, AJ

MCKENNON, MJ

机构：

[1] Department of Chemistry, Colorado State University, Fort Collins

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 09期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)91890-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient route to the title compounds was achieved using the triflates of ketones and phenols followed by Pd-catalyzed CO insertion in the presence of chiral amino alcohols. Aryl, vinyl bromides and 2-pyridone also served as useful substrates.

引用

页码：1181 / 1184

页数：4

共 27 条

[11] THE PALLADIUM-CATALYZED COUPLING OF BETA-TRIFLUOROMETHANESULFONYL ALPHA,BETA-UNSATURATED ESTERS AND KETONES WITH BETA-STANNYL ENOATES - SYNTHESIS OF ELECTRON-DEFICIENT DIENES
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[12] A NOVEL PALLADIUM-CATALYZED PREPARATIVE METHOD OF ALPHA,BETA-UNSATURATED KETONES AND ALDEHYDES FROM SATURATED KETONES AND ALDEHYDES VIA THEIR SILYL ENOL ETHERS
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[15] A ONE-POT PALLADIUM-CATALYZED SYNTHESIS OF BETA,BETA-DIARYLKETONES AND ALDEHYDES FROM ARYL IODIDES AND ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
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[16] NEW METHODS AND REAGENTS IN ORGANIC-SYNTHESIS .39. A NOVEL SYNTHESIS OF ALPHA,BETA-UNSATURATED NITRILES FROM AROMATIC KETONES VIA CYANOPHOSPHATES
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[17] 1,3-REARRANGEMENT OF ALLYLIC PARA-TOLYL SULFONES CATALYZED BY [PD(PPH3)4] AND ITS APPLICATION TO THE SYNTHESIS OF ALPHA,BETA-UNSATURATED KETONES
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[18] Synthesis of Tetracyclic Oxindoles from Isatin Containing Baylis-Hillman Adducts via Pd-Catalyzed Aryl-Aryl Coupling and Reduction with NaBH4
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[20] Direct generation of lithium homoenolates from 3-aryl alpha,beta-unsaturated ketones or esters by an arene-catalysed lithiation: Synthesis of substituted tetrahydrofurans and gamma-butyrolactones
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