A REGIOSELECTIVE ONE-POT SYNTHESIS AND SYNTHETIC APPLICATIONS OF CYANODEOXY SUGARS BY CYANOTRIMETHYLSILANE

被引:0
|
作者
KAZMI, SNUH
AHMED, Z
MALIK, A
AFZA, N
VOELTER, W
机构
[1] UNIV KARACHI,HEJ RES INST CHEM,KARACHI 75270,PAKISTAN
[2] PAKISTAN COUNCIL SCI & IND RES,DIV PHARMACEUT & FINE CHEM,KARACHI 75280,PAKISTAN
[3] UNIV TUBINGEN,INST PHYSIOL CHEM,PHYS BIOCHEM ABT,D-72076 TUBINGEN,GERMANY
关键词
ANHYDRO SUGARS; CYANODEOXY SUGARS; EPOXY RING OPENING; BRANCHED CHAIN PYRANOSES; CYANOTRIMETHYLSILANE;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The regioselective epoxide opening of different 2,3-anhydropyranoses by cyanotrimethylsilane is investigated. The isolated cyanodeoxy pyranoses allow easy access to the corresponding branched-chains aminomethyl sugars by lithium aluminium hydride reduction or sugar amides by controlled acid hydrolysis.
引用
收藏
页码:294 / 302
页数:9
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