Crystal structure of the eta(4)-ketimine titanium complex (diphenylamido-kappa N){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-kappa N-2,C-1}(eta(5)-pentamethylcyclopentadienyl)titanium(IV)

被引：0

作者：

Fischer, Malte ^{[1
]}

Schmidtmann, Marc ^{[1
]}

Beckhaus, Ruediger ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Fak Math & Nat Wissensch, Inst Chem, D-26129 Oldenburg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷

关键词：

crystal structure; titanium; eta(4)-ketimine complex; half-sandwich complex;

D O I：

10.1107/S2056989017017455

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(eta(5)-C10H15)(eta(4)-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central Ti IV atom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an eta(4)-coordination mode and one monodentate diphenylamide ligand. Except for van der Waals forces, there are no significant intermolecular interactions in the crystal.

引用

页码：34 / +

页数：13

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