HETEROMETALLIC-N, PI-COMPLEXES OF TRANSITION-METALS BASED ON MESITYLACETONITRILE

被引:8
|
作者
KAGANOVICH, VS
RYBINSKAYA, MI
机构
[1] A.N. Nesmeyanov Institute of Organoelement Compounds, Academy of Sciences, the USSR, 117813 Moscow
关键词
D O I
10.1016/0022-328X(91)86119-B
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A wide variety of neutral and cationic heterometallic n,pi-complexes of transition metals (MesCH2CNM'L(k)')ML(n) (Mes = mesityl; ML(n) = Cr(CO)3, Mo(CO)3, Co4(CO)9; M'L'(k) = W(CO)5, Mn2(CO)9, Fe(CO)2Cp (in the latter case a cationic complex is formed)) has been synthesised. The photochemical behaviour of the resulting compounds has been studied.
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页码:215 / 224
页数:10
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