Thermal Stability of SrAl2O4: Eu2+, Dy3+ with Long Afterglow Phosphorescence

被引:4
|
作者
Kim, Jin-Ho [1 ]
Lee, Seung-Yong [1 ]
Kim, Tae-Ho [1 ]
Han, Kyu-Sung [1 ]
Hwang, Kwang-Taek [1 ]
Cho, Woo-Seok [1 ]
机构
[1] Korea Inst Ceram Engn & Technol, Icheon Branch, Icheon 467843, South Korea
关键词
Phosphorescent phosphor; SrAl2O4; Eu2+; Dy3+; Reducing atmosphere; Heat treatment; Afterglow;
D O I
10.4191/kcers.2014.51.6.618
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Oxide phosphorescent phosphor has an wide application in ceramic art and decoration due to its chemical and mechanical properties. Here, phosphorescent properties of strontium aluminate phosphor (SrAl2O4 : Eu (2+), Dy3+) emitting yellowish-green light was investigated with thermal treatment at 1250 degrees C under air and reducing atmosphere. The characterizations of thermally treated samples were analyzed using X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive Xray spectroscopy (EDX), fluorescence spectrometer. SrAl2O4 : Eu2+, Dy3+ still showed a good phosphorescent properties after annealing process in reducing atmosphere, while phosphorescence of SrAl2O4 : Eu2+, Dy3+ annealed in air seriously degraded, due to oxidation of Eu2+ to Eu3+ ions. It was also observed that SrAl2O4: Eu2+, Dy3+ annealed in reducing atmosphere emitted yellowishgreen light during 3 h after being exposed to sunlight.
引用
收藏
页码:618 / 622
页数:5
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