BINARY-SYSTEMS IN ELECTROCHEMICAL FLUORINATION .1. SULFAMOYL FLUORIDE AND HYDRAZINIUM(2+) FLUORIDE

被引：2
|
作者：
SARTORI, P
LATTASCH, KD
机构：
[1] Fachgebiet Anorganische Chemie, Universität-Gesamthochschule-Duisburg, 4100 Duisburg 1
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 57卷 / 1-3期
关键词：
D O I：
10.1016/S0022-1139(00)82822-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The effect on the formation of NF3 of H2NSO2F added during the molten-salt electrolysis of ammonium hydrogen fluoride, was studied with varying amounts of hydrogen fluoride. Depending on the conditions of the reaction, the molten fluoride system not only served as solvent and fluorine source for the electrochemical fluorination (ECF) of H2NSO2F, but also as electrolyte. The main products were SO2F2, NF3, N2 and traces of N2F2. Results from similar experiments with N2H6F2 are described.
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页码：113 / 119
页数：7
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