THE EFFECTS OF QUANTUM MODES ON THE ENERGY-GAP LAW FOR ELECTRON-TRANSFER REACTIONS

被引：18
|
作者：
TANG, J
机构：
[1] Chemistry Division, Argonne National Laboratory, Argonne
来源：
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 08期
关键词：
D O I：
10.1063/1.465934
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effects of quantum modes on the free energy relationship for electron-transfer reactions formulated by the ''spin-boson'' model are examined. The modified energy gap law for exothermic electron transfer reactions with quantum modes is derived in a simple analytical form, using the method of steepest descent to avoid the usual multiple convolution integrals.
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页码：5828 / 5830
页数：3
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