(1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS

被引：33

作者：

JUTZI, P ^{[1
]}

SCHNITTGER, J ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

机构：

[1] UNIV LONDON QUEEN MARY COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 08期

关键词：

NONCLASSICAL TL(I)-TL(I) INTERACTIONS; THALLIUM; FULVALENE COMPLEX; (CYCLOPENTADIENYL)THALLIUM COMPLEX; 5,5'-PENTAFULVALENE, 1,1',3,3'-TETRA-TERT-BUTYL-DITHALLIUM;

D O I：

10.1002/cber.19911240804

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,1',3,3'-tetra-tert-butyl-5,5'-dihydropentafulvalenediyldilithium with stoichiometric amounts of thallium chloride affords the dinuclear complex (eta-5:eta-5-tBu4C10H4)Tl2 (2). Compound 2 is air- and moisture-sensitive, and photolabile. It crystallizes in the space group P1BAR and consists of two (cyclopentadienyl)thallium units which are connected by a central C-C bond and twisted against each other by 70-degrees. The monomeric units of 2 form a two-dimensional polymer with d zick-zack chain of Tl atoms and a periphery of substituted cyclopentadienyl ligands. Rather short Tl - Tl contacts of 3.760 and 3.998 angstrom are formed within a dimeric substructure. The geometry of the cyclopentadienyl ligands around the shortest Tl - Tl bond is similar to that predicted by the theory for weak Tl - Tl interactions.

引用

页码：1693 / 1697

页数：5

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