[RE2I2(CO)(6)(SE-7)], A COORDINATION COMPOUND OF ELEMENTAL SELENIUM WITH A TRANSITION-METAL - A SOLUTION AND SOLID-STATE STUDY

被引：17

作者：

BACCHI, A

BARATTA, W

CALDERAZZO, F

MARCHETTI, F

PELIZZI, G

机构：

[1] UNIV PISA, DIPARTIMENTO CHIM & CHIM IND, SEZ CHIM INORGAN, I-56126 PISA, ITALY

[2] UNIV PARMA, IST CHIM GEN & INORGAN, I-43100 PARMA, ITALY

[3] UNIV PARMA, CNR, CTR STUDIO STRUTTURIST DIFFRATTOMETR, I-43100 PARMA, ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199401931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cyclo‐Se7 ligand is bound to two rhenium(I) centers in the title compound 1 (depicted on the right). It arises in the reaction of [Re2I2(CO)6(thf)2] with freshly sublimed elemental selenium in CS2 and is the first complex that contains a discrete molecule of an allotropic modification of selenium as a ligand. These findings add to the understanding of the mechanism of oxidation of metals and low‐valent metal complexes by chalcogens. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：193 / 195

页数：3

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