Di-mu-aqua-bis[aqua(5-carboxylato-1H-1,2,3-triazole-4-carboxylic acid-kappa N-2(3),O-4)lithium]

被引：1
|
作者：
Starosta, Wojciech [1 ]
Leciejewicz, Janusz [1 ]
机构：
[1] Inst Nucl Chem & Technol, Ul Dorodna 16, PL-03195 Warsaw, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813023167
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [Li-2(C4H2N3O4)(2)(H2O)(4)], contains centrosymmetric dinuclear molecules in which two Li I ions are bridged by two water O atoms. The metal ion is coordinated by one N, O-bidentate ligand and three water O atoms (one of them is symmetry generated), with one of the bridging water O atoms in the apical position of a distorted square pyramid. The carboxylate group that participates in coordination to the metal ion remains protonated; the other is deprotonated and coordination inactive. An intramolecular O-H center dot center dot center dot O hydrogen bond between carboxylate groups is observed. In the crystal, dimers are linked by O-H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network.
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页码：M515 / +
页数：7
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