UNIQUE STRUCTURAL FEATURES IN SILVER(I) DITHIOETHER COMPLEXES - THE SINGLE-CRYSTAL STRUCTURES OF [AG-N(PHSCH(2)CH(2)CH(2)SPH)(2N)](BF4)(N)CENTER-DOT-0.5NH(2)O AND[AG-N(MESCH(2)CH(2)CH(2)SME)(N)](BF4)(N)

被引：70
|
作者：
BLACK, JR [1 ]
CHAMPNESS, NR [1 ]
LEVASON, W [1 ]
REID, G [1 ]
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 12期
关键词：
D O I：
10.1039/c39950001277
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The X-ray structure of [Ag-n(PhSCH(2)CH(2)CH(2)SPh)(2n)](n+) shows an infinite array of tetrahedral Ag-I atoms coordinated via one S-donor of four distinct PhSCH(2)CH(2)CH(2)SPh ligands, whereas [Ag-n(MeSCH(2)CH(2)CH(2)SMe)(n)](n+) is a chain polymer involving trigonal (mu(2)-S)(2),S ligation with one S-donor bridging two adjacent Agi centres while the other S-donor of the dithioether ligand is non-bridging.
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页码：1277 / 1278
页数：2
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