ENANTIOSELECTIVE ALKYLATION AT THE ALPHA-POSITION OF CYCLIC-KETONES USING A CHIRAL LITHIUM AMIDE AS A BASE IN THE PRESENCE OF LITHIUM BROMIDE

被引：102

作者：

MURAKATA, M ^{[1
]}

NAKAJIMA, M ^{[1
]}

KOGA, K ^{[1
]}

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 22期

关键词：

D O I：

10.1039/c39900001657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1657 / 1658

页数：2

共 40 条

[31] STEREOSELECTIVE CARBON-CARBON BOND FORMATION - GAMMA-ALKYLATION OF LITHIUM DIANION OF CHIRAL CYCLIC BETA-ENAMINO KETONES
BARTOLI, G
CIMARELLI, C
PALMIERI, G
RAFAIANI, G
TETRAHEDRON-ASYMMETRY, 1992, 3 (06) : 719 - 722
[32] Enantioselective synthesis of novel enantiopure phosphines via reaction of a tricarbonyl(η6-arene)chromium complex with a chiral lithium amide base
Ariffin, A
Blake, AJ
Li, WS
Simpkins, NS
SYNLETT, 1997, (12) : 1453 - 1455
[33] REDUCTION OF VINYLOGOUS THIOESTERS WITH LITHIUM ALUMINUM-HYDRIDE .1. REDUCTION OF BETA-PHENYLTHIO-ALPHA,BETA-UNSATURATED CYCLIC-KETONES
MATOBA, K
TOKIZAWA, M
MORITA, T
YAMAZAKI, T
CHEMICAL & PHARMACEUTICAL BULLETIN, 1985, 33 (01) : 368 - 372
[34] The enantioselective conversion of three-membered ring sulfoxides (episulfoxides) into alkenyl sulfoxides using chiral lithium amide bases
Blake, AJ
Westaway, SM
Simpkins, NS
SYNLETT, 1997, (08) : 919 - &
[35] LITHIUM ALUMINUM-HYDRIDE PARTIALLY DECOMPOSED WITH (-)-N-METHYLEPHEDRINE AND 2-ALKYLAMINOPYRIDINE - AN IMPROVED CHIRAL HYDRIDE USEFUL FOR THE PRACTICAL ASYMMETRIC REDUCTION OF ACHIRAL CYCLIC-KETONES
KAWASAKI, M
SUZUKI, Y
TERASHIMA, S
CHEMICAL & PHARMACEUTICAL BULLETIN, 1985, 33 (01) : 52 - 60
[36] Lithium N-trityl-N-(R)-1-phenethylamide, a readily available and useful base for the enantioselective formation of chiral enolates from achiral ketones
Busch-Petersen, J
Corey, EJ
TETRAHEDRON LETTERS, 2000, 41 (36) : 6941 - 6944
[37] ENANTIOSELECTIVE OPENING OF SPIRO EPOXIDES DERIVED FROM CIS BICYCLO[3.3.0]OCTAN-3,7-DIONE USING CHIRAL LITHIUM AMIDE BASES
LEONARD, J
HEWITT, JD
OUALI, D
SIMPSON, SJ
NEWTON, RF
TETRAHEDRON LETTERS, 1990, 31 (46) : 6703 - 6706
[38] Stereoselective reactions. Part 31: Catalytic asymmetric alkylation of achiral lithium enolates using a chiral tetradentate amine in the presence of an achiral bidentate amine
Imai, M
Hagihara, A
Kawasaki, H
Manabe, K
Koga, K
TETRAHEDRON, 2000, 56 (02) : 179 - 185
[39] NOVEL STRATEGY OF USING A C-2 SYMMETRIC CHIRAL DIETHER IN THE ENANTIOSELECTIVE CONJUGATE ADDITION OF AN ORGANO-LITHIUM TO AN ALPHA,BETA-UNSATURATED ALDIMINE
TOMIOKA, K
SHINDO, M
KOGA, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8266 - 8268
[40] Chiral lithium amide base-mediated rearrangement of bis-protected meso-4,5-dihydroxy cyclohexene oxides:: enantioselective synthesis of (4R,5S)- and (4S,5R)-4,5-bis(tert-butyldimethylsilyloxy)cyclohex-2-enone
O'Brien, P
Poumellec, P
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (15): : 2435 - 2441

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