Bisdiselenolate metal complexes. Synthesis, structure and electrochemical properties

被引：3
|
作者：
Liu, SG
Liu, YQ
Yang, XY
Zhu, DB
机构：
[1] Institute of Chemistry, Academia Sinica, Beijing 100080, Peoples
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 105卷 / 1-4期
关键词：
multi-selenium donor ligand; transition metal complex; crystal structure; electrochemical properties; synthetic metals;
D O I：
10.1080/10426509508042050
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multi-selenium donor ligand 2,2-dicyanoethylene-1,1-diselenolate (DCNSe) has been prepared. The dianionic complex of DCNSe with Ni(II) has been isolated as the tetrabutylammonium (TEA) salt. The compound is characterized by negative ion Fast Atom Bombardment (FAB) mass spectral analysis, Fourier Transform Infrared (FT-IR) spectral analysis, UV-Vis spectral analysis and cyclic voltammetry. The electrochemical properties and crystal structure are studied as well. In addition, the corresponding Cu(II) complex has been isolated as the TEA salt and characterized by negative ion FAB mass spectral analysis and FT-IR spectral analysis.
引用
收藏
页码：83 / 91
页数：9
相关论文
共 50 条
  • [11] New atranes and similar ionic complexes. Synthesis, structure, properties
    Adamovich, Sergey N.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (07)
  • [12] Polymer synthesis with transition metal complexes.
    Grubbs, RH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : C105 - C105
  • [13] Polyphenolate ligands: Synthesis and metal complexes.
    Kayal, A
    Ducruet, AF
    Lee, SC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U740 - U740
  • [14] Synthesis of macrocyclic ligands and metal complexes.
    Clearfield, A
    Kong, DY
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1037 - U1038
  • [15] Electrochemical and structural properties of actinide polyoxoanion complexes.
    Antonio, MR
    Soderholm, L
    Williams, CW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U1054 - U1054
  • [16] Electrochemical studies of transition-metal pyrylium complexes.
    Shaw, MJ
    Ripperda, SE
    Light, S
    Mertz, JN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U156 - U156
  • [17] New phosphorus-containing metal phthalocyanine complexes. Synthesis and spectral and electrochemical studies
    A. V. Ivanov
    K. V. Kabanova
    M. O. Breusova
    I. V. Zhukov
    L. G. Tomilova
    N. S. Zefirov
    Russian Chemical Bulletin, 2008, 57 : 1665 - 1670
  • [18] New phosphorus-containing metal phthalocyanine complexes. Synthesis and spectral and electrochemical studies
    Ivanov, A. V.
    Kabanova, K. V.
    Breusova, M. O.
    Zhukov, I. V.
    Tomilova, L. G.
    Zefirov, N. S.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (08) : 1665 - 1670
  • [19] Platinum Nitrile Complexes. Synthesis and Structure
    V. V. Sharutin
    E. S. Mekhanoshina
    Reviews and Advances in Chemistry, 2023, 13 (3): : 206 - 237
  • [20] Synthesis, structure and properties of the first fluorenyl ansa-yttrocene complexes.
    Lee, MH
    Hong, EK
    Kim, Y
    Kim, J
    Han, YG
    Do, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U40 - U40
12345