STRUCTURE OF (R)-(3-HYDROXY-2,3-DIMETHYLBUTYL)TRIPHENYLPHOSPHONIUM IODIDE N-HYDRATE (N-CONGRUENT-TO-1.3)

被引：5
|
作者：
VANDERSLUIS, P [1 ]
SPEK, AL [1 ]
机构：
[1] STATE UNIV UTRECHT,KRISTAL & STRUCT CHEM LAB,TRANSITORIUM 3,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1990年 / 46卷
关键词：
D O I：
10.1107/S0108270190004140
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C24H28OP+.I-.nH2O (n congruent-to 1.3), M(r) = 513.78, monoclinic, P2(1), a = 9.044 (1), b = 14.173 (1), c = 10.441 (1) angstrom, beta = 115.23 (1)-degrees, V = 1210.7 (2) angstrom 3, Z = 2, D(x) = 1.409 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 13.9 cm-1, F(000) = 522, T = 295 K, R = 0.018 for 2854 unique observed diffractometer data [I greater-than-or-equal-to 2.5-sigma-(I)]. The absolute configuration at the chiral centre is retained during the four-step synthesis of the title compound from (S)-methyl 3-hydroxy-2-methylpropanoate. The structure contains an infinite hydrogen-bond chain in the a direction involving I, H2O and the hydroxyl group.
引用
收藏
页码：2429 / 2431
页数：3
相关论文
共 50 条
  • [21] Crystal structure of 1-(2-(4-chlorophenethyl)-2-hydroxy-3,3-dimethylbutyl)-1H-1,2,4-triazol-4-ium nitrate, C16H23N4O4Cl
    Wang, Hua
    Zhang, Guo-tao
    Li, Hong-ya
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, : 137 - 139
  • [22] Crystal and molecular structure of 4-hydroxy-3-methoxy-4-N-methylstilbazonium iodide C15H16NO2+ • I-
    Zhang, TZ
    Ge, LQ
    Zhang, DC
    Zhang, YQ
    Yu, KB
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (01) : 6 - 10
  • [23] Synthesis and Structure Investigations of Potential Sedative and Anticonvulsant Hydroxy- and Acetoxy-N-(3-oxobutyl)-pyrido[2,3-d]pyridazinonesa
    Edith Gößnitzer
    Ales Krbavcic
    Winfried Wendelin
    Marija Krbavcic
    Monatshefte für Chemie / Chemical Monthly, 2002, 133 : 1177 - 1185
  • [24] Synthesis and structure investigations of potential sedative and anticonvulsant hydroxy- and acetoxy-N-(3-oxobutyl)-pyrido[2,3-d]pyridazinones
    Gössnitzer, E
    Krbavcic, A
    Wendelin, W
    Krbavcic, M
    MONATSHEFTE FUR CHEMIE, 2002, 133 (09): : 1177 - 1185
  • [25] Crystal structure of (2R*,3R*)-3-amino-2-ethyl-N-(2-hydroxy-1,1-dimethylethyl)-3-p-methoxyphenylpropanamide, C17H28N2O3
    Capriati, Vito
    Degennaro, Leonardo
    Florio, Saverio
    Luisi, Ronzo
    Moliterni, Anna
    Rizzi, Rosanna
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (04): : 483 - 484
  • [26] N-AMINOAZOLES .3. MOLECULAR-STRUCTURE AND MULTINUCLEAR NMR-STUDY OF 1,3-DIAMINOBENZIMIDAZOLIUM CHLORIDE HYDRATE AND 1-AMINO-3-METHYLBENZIMIDAZOLIUM IODIDE
    POZHARSKII, AF
    KUZMENKO, VV
    FOCESFOCES, C
    LLAMASSAIZ, AL
    CLARAMUNT, RM
    SANZ, D
    ELGUERO, J
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (04): : 841 - 846
  • [27] MOLECULAR-STRUCTURE OF CIS-2-(N-PROPIONYL-N-ETHYLAMINO)-3-(2',5'-DIHYDROXYPHENYL)-5-HYDROXY-3-METHYL-2,3-DIHYDROBENZOFURAN DETERMINED BY X-RAY AND NMR METHODS
    URBANCZYKLIPKOWSKA, Z
    KRAJEWSKI, JW
    GLUZINSKI, P
    KOZERSKI, L
    DOBLER, M
    JOURNAL OF MOLECULAR STRUCTURE, 1984, 125 (3-4) : 321 - 329
  • [28] Crystal structure of N-[(2S,5R)-4-oxo-2,3-diphenyl-1,3-thiazinan-5-yl]acetamide 0.375-hydrate
    Yennawar, Hemant P.
    Singh, Harnoor
    Silverberg, Lee J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 62 - +
  • [29] Crystal and Molecular Structure of 4-Hydroxy-3-Methoxy-4-N-Methylstilbazonium Iodide C15 H16 NO2 +·I-CrystalandMolecularS
    ZHANG Tian Zhu a GE Li Qin b ZHANG De Chun b ZHANG Yan Qiu b YU Kai Bei c a(Department of Preventive Medicine
    结构化学, 2000, (01) : 6 - 10
  • [30] Crystal structure of pentakis(imidazole-N)copper(II) bis(3-hydroxy-2-naphthoate) hydrate, [Cu(C3H3N2)5](C11H7O3)2 • H2O
    Zhao, Xiaolei
    Zhang, Ke
    Xue, Qing
    Huo, Yu
    Wang, Gaopeng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (03): : 515 - 516
12345