TRANSMETALATION BETWEEN VINYLIC TELLURIDES AND HIGHER-ORDER CYANOCUPRATES - INSITU FORMATION OF VINYL CUPRATES

被引：49

作者：

COMASSETO, JV

BERRIEL, JN

机构：

[1] Instituto de Química, Universidade de São Paulo, CEP 01498, Sao Paulo, S.P.

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 11期

关键词：

D O I：

10.1080/00397919008053089

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylic tellurides react with higher order dialkylcyanocuprates leading to mixed vinylcyanocuprates with retention of the olefin geometry. The mixed vinylcyanocuprates react with enones giving the 1,4-addition products in good yields. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1681 / 1685

页数：5

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