CHIRAL RECOGNITION OF OLEFINS BY H-1-NMR SPECTROSCOPY IN THE PRESENCE OF A CHIRAL DIRHODIUM COMPLEX

被引：67
|
作者：
WYPCHLO, K [1 ]
DUDDECK, H [1 ]
机构：
[1] UNIV HANNOVER,INST ORGAN CHEM,D-30167 HANNOVER,GERMANY
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 01期
关键词：
D O I：
10.1016/S0957-4166(00)80477-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new NMR method using 1 for chiral recognition of olefins is presented and compared with Mannschreck's method using Yb(hfc)(3)/Ag(fod). It was found that the spectroscopic results are comparable but the new rhodium reagent is much easier to handle and can readily be recovered. [GRAPHICS] ty.
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收藏
页码：27 / 30
页数：4
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