SYNTHESIS AND PROPERTIES OF PALLADIUM(II) COMPLEXES WITH SULFUR LIGANDS

被引：16
|
作者：
KAHN, ES
RHEINGOLD, AL
SHUPACK, SI
机构：
[1] VILLANOVA UNIV,DEPT CHEM,VILLANOVA,PA 19085
[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE
来源：
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1993年 / 23卷 / 09期
关键词：
D O I：
10.1007/BF01187271
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Complexes of L-2 thiolhistidine (th) and 2-mercaptoimidazole (miz)with Pd(II) were synthesized; Pd(th)(4)(NO3)(2) and Pd(miz)(4)Cl-2, and their structure determined by FTIR, UV/VIS, NMR, mass spectroscopy, and X-ray crystallography. For comparison, a Pd(II) complex with thiourea (tu), Pd(tu)(4)Cl-2, was prepared. This compound has been reported in the literature. Spectral evidence indicates a single coordination site between the Pd(II) and S for all complexes. A Pd-S stretch band was identified for all complexes. NMR spectra provided evidence for deshielding effects in the; complexes from that of its ligands. Charge transfer bands were identified in the UV!VIS spectra for the new complexes as well. The crystal structure for Pd(miz)(4)Cl-2 was determined. Unit cell data was found to be: a = 8.102(3)Angstrom, b = 8.300(3)Angstrom, c = 8.304(3)Angstrom. The crystal system is triclinic and the space group is P $$($) over bar 1.
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收藏
页码：697 / 710
页数：14
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