EVALUATION OF THE KINETIC AND THERMODYNAMIC PARAMETERS FOR THE THERMAL-DECOMPOSITION OF BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(IV) N,N'-BIS(2-HYDROXYNAPHTHALENE-1-CARBALDENE)ALKENEDIAMINES

被引：0

作者：

JOSHI, V ^{[1
]}

JAIN, SK ^{[1
]}

KAUSHIK, NK ^{[1
]}

机构：

[1] UNIV DELHI,DEPT CHEM,DELHI 110007,INDIA

来源：

THERMOCHIMICA ACTA | 1992年 / 203卷

关键词：

D O I：

10.1016/0040-6031(92)85206-B

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The course of the thermal degradation of (eta-5-C5H5)2Ti(SB) complexes (SB, Schiff base) has been investigated using thermogravimetric (TG) and differential thermal analysis (DTA) techniques. The order of reaction and activation energy were calculated from the TG curves and the enthalpy change was calculated from the DTA curve. From the evaluated kinetic parameters, a mechanism was suggested for the thermal degradation. Spectral studies (IR, H-1-NMR and UV-visible) indicate that these complexes are tetradentate and octahedral.

引用

页码：311 / 320

页数：10

共 38 条

[1] BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(IV) COMPLEXES OF MONOFUNCTIONAL BIDENTATE 2-HYDROXYNAPHTHALENE-1-CARBALIDIMINES
JOSHI, V
JAIN, SK
KAUSHIK, NK
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[2] (CHLORO) (N,N-ALKYLCYCLOHEXYLDITHIOCARBAMATO)BIS (ETA-5-CYCLOPENTADIENYL)TITANIUM(IV)-ZIRCONIUM(IV) COMPLEXES
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[3] SYNTHESIS AND CHARACTERIZATION OF BIS(ETA-5-CYCLOPENTADIENYL)-N,N'-DISUBSTITUTED SCHIFF-BASE COMPLEXES OF TITANIUM(IV)
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[4] BIS-ETA-5-CYCLOPENTADIENYL AND BIS-ETA-5-METHYLCYCLOPENTADIENYL N,N-DIALKYLDITHIOCARBAMATO(CHLORO)TITANIUM(IV) COMPOUNDS
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BHUSHAN, B
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[5] Bis(mu(2) isopropylimido-kappa(2) N:N) bis[(eta(5) cyclopentadienyl)(ethenolato- kappa O)titanium(IV)]
Haehnel, Martin
Spannenberg, Anke
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M16 - +
[6] SOME REACTIONS OF 8-QUINOLINOL-N-OXIDE WITH "BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM DICHLORIDE
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[7] BIS(ETA-5-CYCLOPENTADIENYL)BIS(METHANETHIOLATO)TITANIUM(IV), (ETA-5-C5H5)2TI(SCH3)2
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[8] THE MOLECULAR-STRUCTURE OF BIS(ETA-5-CYCLOPENTADIENYL)BIS(ETHYLTHIOLATO)TITANIUM(IV), (ETA-5-C5H5)2)TI(SC2H5)2
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ACTA CRYSTALLOGRAPHICA SECTION A, 1984, 40 : C290 - C290
[9] LONG ZR S BONDS IN THE STRUCTURE OF THE STEREOCHEMICALLY NONRIGID COMPLEX, BIS(ETA-5-CYCLOPENTADIENYL)(N,N-DIMETHYLDITHIOCARBAMATO)PHENOXYZIRCONIUM(IV)
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 1811 - 1814
[10] {N, N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl] methylamine-kappa(2) P, P'}bis(eta(5)-cyclopentadienyl) titanium(II)
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