CONFORMATIONAL CHANGE OF DIETHYLENE GLYCOL DIETHYL-ETHER DUE TO CATION-CAPTURE AND WATER-ACCOMMODATION

被引：3
|
作者：
FUKUSHIMA, K
SAKURADA, K
机构：
[1] Department of Chemistry, Faculty of Science, Shizuoka University, 836 Oya, Shizuoka
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 240卷
关键词：
D O I：
10.1016/0022-2860(90)80510-Q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Raman spectra of diethylene glycol diethyl ether were measured in the liquid and solid states, and stable comformers identified from the solvent effect on the various bands and by normal vibration calculations. Remarkable spectral changes caused by interaction of the substance with cations and water were observed. Molecular mechanics calculation for diethylene glycol diethyl ether-water systems provided an optimized structure which explains some of these spectral changes. Structural differences were also found among the various cation complexes of diethylene glycol diethyl ether. © 1990.
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页码：201 / 212
页数：12
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