Excited state dipole moments of phenanthrene: Electric field modulation of the luminescence

被引:16
|
作者
Hochstrasser, R. M. [1 ]
Noe, L. J.
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
[2] Univ Penn, Res Struct Matter Lab, Philadelphia, PA 19104 USA
关键词
D O I
10.1016/0009-2614(70)85116-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dipole moments of the lowest (3)pi pi* and (1)pi pi* excited states of phenanthrene shave been determined by Stark modulation spectroscopy and are <= 0.12 D and 0.34 D respectively. The method is extremely sensitive and makes possible quantitative investigations of relatively small dipole moment changes of broad banded spectral systems.
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页码:489 / 492
页数:4
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