BLOCK-COPOLYMER-INDUCED STRUCTURE FORMATION IN MICROEMULSIONS

被引:15
|
作者
HILFIKER, R [1 ]
EICKE, HF [1 ]
STEEB, C [1 ]
HOFMEIER, U [1 ]
机构
[1] UNIV BASEL,INST PHYS CHEM,KLINGELBERGSTR 80,CH-4056 BASEL,SWITZERLAND
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 03期
关键词
D O I
10.1021/j100156a082
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transient electric birefringence measurements were performed on water/AOT (sodium bis(2-ethylhexyl) sulfosuccinate)/isooctane microemulsions with various amounts of block-copoly(oxyethylene/isoprene/oxyethylene) added. We could show that addition of the copolymer leads to a formation of nanodroplet (ND)-copolymer-aggregates. The contributions of NDs and aggregates to the induced birefringence could easily be separated because the NDs exhibited a negative and the aggregates a positive induced birefringence and because the time scales corresponding to the two processes were different.
引用
收藏
页码:1478 / 1480
页数:3
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