PREPARATIVE DERIVATIZATION OF ENDO-DICYCLOPENTADIENE VIA METALATION

被引：2
|
作者：
KUMAGAI, T
AGA, M
OKADA, K
ODA, M
机构：
[1] OSAKA UNIV, FAC SCI, DEPT CHEM, TOYONAKA, OSAKA 560, JAPAN
[2] EHIME UNIV, FAC EDUC, DEPT CHEM, MATSUYAMA, EHIME 790, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 04期
关键词：
D O I：
10.1246/bcsj.64.1428
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
endo-Dicyclopentadiene has been selectively metallated with the base complex BuLi.t-BuOK in hexane at the olefinic positions in the norbornene moiety and a number of derivatives prepared by reaction of the metallated intermediate with electrophilic reagents. In particular, bromodicyclopentadiene thus obtained is a useful stock precursor for lithiodicyclopentadiene.
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页码：1428 / 1430
页数：3
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