SOLVENT-EXTRACTION OF LANTHANIDES WITH N-M- AND N-P-METHOXYBENZOYL-N-PHENYLHYDROXYLAMINE

被引：8

作者：

INOUE, S

机构：

[1] Department of Environmental Engineering, Kitami Institute of Technology, Kitami-shi, Hokkaido

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1991年 / 9卷 / 04期

关键词：

D O I：

10.1080/07366299108918072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent extraction of lanthanides with N-o-methoxy-(o-MBPHA), N-m-methoxy- (m-MBPHA) and N-p-methoxybenzoyl-N-phenylhydroxylamine (p-MBPHA), respectively, in chloroform was studied. The selected lanthanides (Yb, Ho, Eu, Pr and La) were all found extract with m- and p-MBPHA as self-adducts of the form LnL32HL, where L and HL denote the ligand anion and neutral ligand, respectively. The extraction constant and separation factors for the lanthanides with m- and p-MBPHA were evaluated.

引用

页码：593 / 606

页数：14

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