STRUCTURE OF DIMETHYL 9-CHLORO-9,10-DIHYDRO-9,10-ETHENOANTHRACENE-11,12-DICARBOXYLATE

被引:1
|
作者
TROTTER, J
YEE, VC
机构
关键词
D O I
10.1107/S0108270192011880
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two ester groups have different orientations, with C=C-C=O torsion angles of -165.7(3) and -89.4(4)degrees respectively for the groups remote from and adjacent to the Cl substituent. The remote ester group is therefore fully conjugated with the C=C double bond [cos2(angle) = 0.94] and the adjacent group nonconjugated [cos2(angle) = 0], presumably as a result of steric effects.
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页码:846 / 848
页数:3
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