SYNTHESIS AND STRUCTURE OF A NOVEL MICROPOROUS GALLOPHOSPHATE, NA3GA5(PO4)(4)O-2(OH)(2)CENTER-DOT-2H(2)O

被引:32
|
作者
ATTFIELD, MP
MORRIS, RE
GUTIERREZPUEBLA, E
MONGEBRAVO, A
CHEETHAM, AK
机构
[1] UNIV CALIF SANTA BARBARA,DEPT MAT,SANTA BARBARA,CA 93106
[2] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN
关键词
D O I
10.1039/c39950000843
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of the title compound, Na3Ga5(PO4)(4)O-2(OH)(2).2H(2)O, consists of GaO6 octahedra, GaO5 trigonal bipyramids and PO4 tetrahedra which, by sharing edges and corners, form an open Structure containing channels (ca. 4 Angstrom diameter) running along the [001] direction; two water molecules per formula unit can be desorbed.
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页码:843 / 844
页数:2
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