TRANSITION-METAL MEDIATED ASYMMETRIC-SYNTHESIS .14. A NEW STRATEGY FOR THE REACTIVATION OF TRICARBONYLIRON COMPLEXES

被引：2
|
作者：
ALEXANDER, IJ
HALES, NJ
STEPHENSON, GR
机构：
[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND
[2] ICI PLC,DIV PHARMACEUT,MACCLESFIELD SK10 4TG,CHESHIRE,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 453卷 / 01期
关键词：
D O I：
10.1016/0022-328X(93)80334-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Protonation of an exo-substituted eta4-triene complex results in a hydrogen shift that removes the effect of a blocking group and so provides a means of regenerating the eta5-cation in situations in which hydride abstraction would be prevented by the exo-substituent.
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页码：111 / 115
页数：5
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