SYNTHESIS AND THERMOCHEMISTRY OF TELLURITES OF SOME s-d ELEMENTS

被引：0

作者：

Rustembekov, K. T. ^{[1
]}

机构：

[1] Karaganda State Univ, Karaganda, Kazakhstan

来源：

BULLETIN OF THE UNIVERSITY OF KARAGANDA-CHEMISTRY | 2010年 / 58期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tellurites of some s- d- elements have been synthesised for the first time by solid- phase method. Isobaric heat capacity, on the basis of which the dependence equations Cp 0 f( T) were selected and thermodynamic functions were determined, was studied by the method of dynamic calorimetry in the range of 298,15- 673.. The.- shaped effects: Na2Zn( TeO3) 2 ( 348, 523 K), CaZn( TeO3) 2 ( 348, 473 K), MgCd( TeO3) 2 ( 523 K), CaCd( TeO3) 2 ( 323, 523 K), connected, probably, with phase transition of the second order was observed on dependence diagram Cp 0 f(

引用

页码：42 / 47

页数：6

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