VAPOR-LIQUID-EQUILIBRIA OF BINARY-MIXTURES OF BETA-PINENE WITH LIMONENE AND P-CYMENE AT ATMOSPHERIC-PRESSURE

被引：18
|
作者：
BERNARDOGIL, MG
RIBEIRO, MA
机构：
来源：
FLUID PHASE EQUILIBRIA | 1993年 / 85卷
关键词：
EXPERIMENTS; DATA; VLE; TERPENES;
D O I：
10.1016/0378-3812(93)80010-K
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Vapor-liquid equilibrium data for the binary systems beta-pinene + limonene and beta-pinene + pq-cymene were determined at atmospheric pressure in an Othmer equilibrium still. Vapor pressures of pure components were measured and the data correlated with the Antoine equation. Parameters for the Van-Laar, Margules, Wilson, NRTL and UNIQUAC equations were calculated with the aid of a Nelder - Mead technique to minimize an objective function based on the total pressure. Predictions with the UNIFAC method were also obtained.
引用
收藏
页码：153 / 160
页数：8
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